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Industry: Petroleum and petrochemical industry

Overall solution for gas safety monitoring in the petroleum and petrochemical industry

Overall solution for gas safety monitoring in the petroleum and petrochemical industry

Industry Pain Points

The petroleum and petrochemical industry is characterized by the "highest density of major hazard sources" — with highly integrated facilities such as kiloton-scale tank farms, atmospheric and vacuum distillation units, catalytic cracking units, hydrofining units, aromatics/olefins units, polyolefin units, and tank farm docks, spanning over 100 types of gases: H2S (sulfur-containing crude oil at 1000+ ppm), combustible LEL (methane/ethane/propylene/butadiene/benzene), highly toxic gases (CO/NH3/phosgene/acrylonitrile), PM2.5 + VOCs + boundary odor. A ten-million-ton refinery processes an average of 30,000 to 50,000 tons of oil and gas daily, with 50,000 to 100,000 potential leakage points. The industry is subject to the strictest regulations: GB 50493 + GB 18218 + GB 30871 + the "dual control" measures of the Emergency Management Bureau + the "three simultaneous" review + LDAR statutory requirements + the maritime bureau's regulations on oil and gas recovery at docks + the long-distance pipeline regulations. A single major accident can often result in social impact, political risk, and fines and compensation amounting to billions of yuan (such as the incidents at Dalian New Port in 2010 and Tianjin Port in 2015).

Solution Overview

Youri'an provides integrated monitoring for the entire refinery plant + tank farm + dock + long-distance pipeline: ① **Atmospheric and vacuum distillation + catalytic cracking + hydrogenation unit**: H2S (measuring range 0-1000 ppm, core risk of sour crude) + LEL + benzene + CO + phosgene PID multi-probe SIL 2-3 level; ② **Tank farm**: floating roof tank / internal floating roof / spherical tank / vertical tank with multi-point coverage on each tank top + cofferdam + loading and unloading platform; ③ **Dock oil and gas recovery**: VOC online monitoring during ship loading process + oil and gas recovery efficiency calculation + environmental compliance reporting to the maritime bureau; ④ **Long-distance pipeline**: station + block valve well + fixed LEL at crossing points + unmanned aerial vehicle (UAV) along the line + satellite remote sensing composite inspection; ⑤ **Boundary VOC + odor grid**: intelligent source tracing with 30-50 monitoring stations; ⑥ **Central SIS / emergency platform**: interlocked with DCS / SIS / FGS for fire gas detection, hierarchical ESD start-stop + accident water pool + video linkage + plant GIS risk map. Equipment explosion-proof grade Ex d IIC T6 (the strictest grade for IIC category containing hydrogen/acetylene).

## Recommended Configuration Matrix (by Process Unit)

### Device Area
– **Atmospheric and vacuum**: H2S (PC-TWA 10 mg/m³) + LEL + benzene PID + CO
– **Catalytic cracking**: H2S (regenerator flue gas SO2 + plant area H2S) + NOx combined SIS
– **Hydrogenation refining**: H2 + H2S (high-pressure leakage, laser remote sensing composite) + explosion-proof Ex d IIC T1 (the strictest level for hydrogen gas)
– **Reforming + Aromatics**: Benzene / Toluene / Xylene PID (PPB level) + LEL
– **Ethylene cracking**: ethylene + propylene + butadiene (carcinogen) + high-temperature furnace cracking gas
– **Polyolefin**: dust + electrostatic monitoring + LEL

### Tank Farm
– **Crude oil tank**: H2S (high concentration 0-1000 ppm) + LEL + tank top breather valve VOC + floating roof tilt monitoring
– **Finished oil tank**: Benzene PID + LEL + Vapor space gas phase
– **Spherical tank LPG / olefins**: LEL + explosion-proof IIB + cofferdam isolation
– **Tank farm cofferdam**: 4-6 points per cofferdam for LEL + H2S detection at a height of 0.3m

### Oil and Gas Recovery at Terminals
– Fixed VOC flow rate + concentration in shipment pipelines (calculated recovery efficiency ≥ 95%)
– Oil receiving and dispensing process: LEL + static alarm + grounding status
– Crew members are equipped with a portable 4-in-1 device

### Long-distance pipeline
– Station LEL + H2S + flow rate + pressure interlock
– Fixed NB-IoT methane monitoring for valve interceptors (1 probe per well, 5-year battery)
– Fixed TDLAS laser methane telemetry equipped on drones for line patrols (1-2 times per month)
– Dual monitoring via satellite and fiber-optic cables for critical crossing points (rivers/highways/railways)

## Key Technical Specifications

– Explosion-proof: Ex d IIC T6 (covering the most stringent level for H2/acetylene)
– Protection: IP66 – IP67 (corrosion in coastal chemical sites + high humidity)
– SIL level: SIL 2 – SIL 3 (integrated with SIS safety instrumented system)
– Range: H2S 0-1000 ppm / LEL 0-100% / Benzene 0-100 ppm (PID sensitivity of 0.01 ppm)
– Response time: T90 < 10 seconds (toxic gases)
– Operating temperature: -40℃ ~ +75℃
– Communication: HART + Modbus + Profibus + FOUNDATION Fieldbus

## Implementation Essentials

1. **SIL assessment for the entire device is mandatory**: According to GB 21109 / IEC 61508, assess the SIL level for each circuit, with a focus on critical SIL 3
2. **LDAR Compliance**: Conduct leak detection for flange, valve, and pump sealing points four times a year, utilizing a combination of PID inspection and infrared imaging, and submit the data to the Environmental Protection Bureau
3. **Emergency Linkage**: Ultra-high Alarm → ESD (Emergency Shutdown) + Tank Farm Interlock Shutdown + Activate Accident Water Pool + Emergency Broadcast + Recommend Evacuation Routes via Plant GIS + Warning to Surrounding Communities
4. **Accurate Carbon Emission Measurement**: Flare Tail Gas Burnout Rate + Tank Top VOC Emissions + Shipment Oil and Gas Recovery Efficiency = Accurate Greenhouse Gas Accounting for the Entire Plant, Aligned with ESG Disclosure

## Regulatory Basis

– GB 50493-2019 Standard for Design of Detection and Alarm Systems
– GB 18218-2018 Identification of Major Hazard Installations
– GB 30871-2022 Safety Code for Special Operations in Hazardous Chemical Enterprises
– GB 21109 / IEC 61508 Functional Safety of Safety Instrumented Systems
– HJ 1093-2020 Continuous Monitoring of Pollution Source Flue Gas
– HJ 733-2014 Control of Volatile Organic Compound (VOC) Emissions from Leaks and Open Liquid Surfaces
– AQ 3013 General Specification for Chemical Standardization
– Long-distance pipeline method (2013) + Maritime Safety Administration's oil and gas recovery SOP

## Applicable Customers

Refineries of Sinopec / PetroChina / CNOOC / Sinochem Group, independent refining and chemical companies (Hengli / Zhejiang Petrochemical / Shenghong / Dongfang Shenghong / Wanhua Yantai / Dalian Hengli), coal chemical enterprises (Shenhua Coal Chemical / Yankuang Yulin / Middling Coal Shaanxi Yulin), terminal companies (China Port Group / Shanghai Port Group / Ningbo Port), long-distance pipeline operators (National Gas Grid / natural gas in various provinces).

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